Planning to Create a Beginners Guide to VS 2010, .NET 4, etc.

I want to look at this through the eyes of someone that is new to the .NET world and where they would begin with the slew of technology, libraries, frameworks, etc. available. I want to go beyond the "Here is some cool technology and here is a cool example" to here is how you would write some quality code, including unit test, acceptance test, build automation, useful patterns. In short, teach the things early that often scare newbies and are needed to deliver quality code. If you have any suggestions, please comment here. Otherwise, I will be beginning with an ASP.NET MVC application or Silverlight most likely, while utilizing as many of the principles to quality development in the training.